Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II ) dihydrate

作者:Gao Feng*; Yao Chang Sheng; Lu Zai Sheng; Shi Yan Hui
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M213-U961.
DOI:10.1107/S1600536811001620

摘要

In the title compound, [Mn(C6H4N5O)(2)(H2O)(2)]center dot 2H(2)O, the Mn-II ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1-oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry. All the water H atoms are involved in O-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds with uncoordinated water O atoms and tetrazole N atoms, which link the molecules into a three-dimensional network.

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