A new 2-D cobalt coordination polymer with the flexible 2-(1H-imidazole-1-yl)acetate: synthesis, structure, and characterization

作者：Wang Yong Tao^*; Tang Gui Mei; Zhang Yong Chun; Wan Wen Zhu; Yu Jian Chao; Li Tian Duo; Cui Yue Zhi

来源：Journal of Coordination Chemistry, 2010, 63(9): 1504-1513.

DOI：10.1080/00958972.2010.481717

• Metal coordination polymer
• Coordination modes
• Cobalt complex
• 2-D
• (3
• 6) Topology
• 2-(1H-imidazole-1-yl)acetate

A new cobalt coordination polymer with linking unit 2-(1H-imidazole-1-yl)acetate (ima), [Co(ima)2]n (1), has been synthesized and structurally characterized by elemental analysis, IR spectra, and X-ray single-crystal diffraction. The X-ray analysis indicates that a neutral 2-D coordination polymer with (3,6) topology was obtained, which shows a 3-D supramolecular network through C-H center dot center dot center dot O weak interactions. Complex 1 displays mild antimicrobial activity against Achromobacter xylosoxidans ATCC 2706, Bacillus subtilis ATCC 6633, and Candida albicans ATCC 90028, respectively. The magnetic and thermal gravimetric properties for 1 have been investigated and discussed.

• 出版日期2010
• 单位齐鲁工业大学