Limits of the plane wave approximation in the measurement of molecular properties

作者：Walters Zachary B^*; Tonzani Stefano; Greene Chris H

来源：Journal of Physical Chemistry A, 2008, 112(39): 9439-9447.

DOI：10.1021/jp8031226

Rescattering electrons offer great potential as probes of molecular properties on ultrafast timescales. The most famous example is molecular tomography, in which high harmonic spectra of oriented molecules are mapped to "tomographic images" of the relevant molecular orbitals. The accuracy of such reconstructions can be greatly affected by the distortion of scattering wave functions from their asymptotic forms due to interactions with the parent ion. We investigate the validity of the commonly used plane wave approximation in molecular tomography, showing how such distortions affect the resulting orbital reconstructions.

• 出版日期2008-10-2
• 单位西北大学