An organometallic dithiolene complex exhibiting electrochemically initiated hydrogen generation

作者：Nomura Mitsushiro^*; Fujita Takayama Chikako; Yagisawa Takayoshi; Sugiyama Toru; Kajitani Masatsugu

来源：Dalton Transactions, 2013, 42(14): 4764-4767.

DOI：10.1039/c3dt50193k

We clarify the electrochemical behavior of an organometallic cobalt dithiolene complex (1-NH) with a secondary sulfonyl amide (-NHSO2-) substituted Cp ligand involving proton dynamics. The reductions of 1-NH and its deprotonated derivative (1-N-) are centered on the CpCoS2 moiety. The 2e(-) reduction of 1-NH quantitatively gives 1-N- with hydrogen generation.

• 出版日期2013