Asymmetric addition of pyridine to 1,4-bis(ethynyl)bicyclo[2.2.2]octane: dissymmetrical rotator ligands illustrated in dpppPt(II) and [Re6Se8](2+) complexes and an amphidynamic hydrogen bonded framework solid

作者：Lemouchi C; Barres A L; Meziere C; Rondeau D; Zorina L; Wzietek P; Batail P^*

来源：Dalton Transactions, 2011, 40(32): 8075-8078.

DOI：10.1039/c1dt10913h

A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2] octane cores allowing for their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal-rotor hybrids like a corner-shaped mononuclear complex, an octahedral hexanuclear metal complex, and a framework solid with a rather slow rotator.

• 出版日期2011