Nonpolar, polar, and associating solutes in ionic liquids

作者:Lopes Jose N Canongia*; Gomes Margarida F Costa; Padua Agilio A H
来源:Journal of Physical Chemistry B, 2006, 110(34): 16816-16818.
DOI:10.1021/jp063603r

摘要

The existence of microphase segregation between polar and nonpolar domains in ionic liquids changes the way in which solvation can be understood in these media. Here, we perform a structural analysis on the solvation of nonpolar, polar, and associating solutes in imidazolium-based ionic liquids, where this novel way of understanding their nature as microsegregated solvents is correlated with their ability to interact with different species in diverse and complex ways.

  • 出版日期2006-8-31