Hydroxyl Radical Control through Hydrogen Bonding: Photolysis of Platinum(IV)hydroxido Complexes with Intramolecular H-Bonding

作者：Wickramasinghe Lasantha A; Sharp Paul R^*

来源：Organometallics, 2015, 34(14): 3451-3454.

DOI：10.1021/acs.organomet.5b00292

By introducing hydrogen-bonding groups into the coordination sphere Of Pt(IV) hydroxido complexes photogenerated hydroxyl radicals are tethered and directed to abstract a hydrogen atom from the ethyl group of a triethylphosphine ligand, even at 25 degrees C, to yield phosphaplatinacycle complexes.

• 出版日期2015-7-27