HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND ELECTROCHEMICAL BEHAVIOR OF 2D HYBRID COORDINATION POLYMER

作者：Fan, Weiqiang^*; Zhu, Lin; Shi, Weidong; Chen, Fuxiao; Bai, Hongye; Song, Shuyan; Yan, Yongsheng

来源：Functional Materials Letters, 2013, 6(3): 1350027.

DOI：10.1142/S1793604713500276

• Hydrothermal synthesis
• crystal structure
• electrochemical behavior

A novel metal-organic coordination polymer [Cu(phen)(L)(0.5)(H2O)](n) (H4L (N,N'-5,5'-bis(isophthalic acid)-p-xylylenediamine, and phen = 1,10-phenanthroline) has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction. The crystallographic data show that the title compound crystallizes in monoclinic space group P2(1)/n with a = 10.682(2), b = 15.682(3), c = 11.909(2) angstrom, beta = 91.39(3)degrees, V = 1994: 3(7) angstrom(3), C24H17CuN3O5, M-r = 490.95, D-c = 1.635 g/cm(3), F(000) = 1004, Z = 4, mu(MoK alpha) = 1.141 mm(-1), the final R = 0.0418 and wR = 0.0983 for 3578 observed reflections (I > 2 sigma(I)). The structural analyses reveal that the title compound exhibits shows a 2D layer structure, which are further linked by hydrogen bonding interactions to form a three-dimensional supramolecular network. In addition, the thermal stability and electrochemical behavior of title compound has been studied. CCDC: 900413.

• 出版日期2013-6
• 单位江苏大学