Application of RCM reaction in the construction of ABC ring of micrandilactone A

作者:Zhang YD; Tang YF; Luo TP; Shen J; Chen JH; Yang Z*
来源:Organic Letters, 2006, 8(1): 107-110.
DOI:10.1021/o1052630h

摘要

The functionalized ABC ring system of micrandilactone A was successfully constructed in 14 steps. The key reactions in this synthesis are the intermolecular Diels-Alder reaction (IMDA) and the eneyne ring-closing metathesis (RCM) reaction.