A facile single crystal to single crystal transition with significant structural contraction on desolvation

作者：Knichal Jane V; Gee William J; Burrows Andrew D^*; Raithby Paul R; Teat Simon J; Wilson Chick C

来源：Chemical communications, 2014, 50(92): 14436-14439.

DOI：10.1039/c4cc06587e

5-Ethynyl-1,3-benzenedicarboxylic acid (H(2)ebdc) reacted with lead(II) acetate trihydrate yields a 1D ladder network, [Pb(ebdc)(MeOH)](2)center dot H2O (1). Removing crystals of 1 from the mother liquor results in a facile single crystal to single crystal transition, yielding 2D [Pb(ebdc)] net (2) with a change in space group from I2/a to P (1) over bar.

• 出版日期2014