Flexible Cu(In, Ga)Se-2 thin-film solar cells on polyimide substrate by low-temperature deposition process

作者：Zhang Li^*; He Qing; Jiang Wei Long; Li Chang Jian; Sun Yun

来源：Chinese Physics Letters, 2008, 25(2): 734-736.

The electrical and structural properties of polycrystalline Cu(In,Ga)Se-2 films grown on polyimide (PI) substrates below 400 degrees C via one-stage and three-stage co-evaporation process have been investigated by x-ray diffraction spectra (XRD), scanning electron microscopy (SEM) and Hall effect measurement. As shown by XRD Spectra, the stoichiometric CIGS films obtained by one-stage process exhibit the characteristic diffraction peaks of the (In0.68Ga0.32)(2)Se-3 and Cu(In0.7Ga0.3)(2)Se. It is also found that the film structures indicate more columnar and compact than the three-stage process films from SEM images. The stoichiometric CIGS films obtained by three-stage process exhibit the coexistence of the secondary phase of (In0.68Ga0.32)(2)Se-3, Cu2-xSe and Cu(In0.7Ga0.3)(2)Se. High net carrier concentration and sheet conductivity are also observed for this kind of film, related to the presence of Cu2-xSe phase. As a result, when the CIGS film growth temperature is below 400 degrees C, the three-stage process is inefficient for solar cells. By using the one-stage co-evaporation process, the flexible CIGS solar cell on a PI substrate with the best conversion efficiency of 6.38% is demonstrated (active area 0.16 cm(2)).

• 出版日期2008-2
• 单位南开大学