A new polyoxotungstate-based {W72V30} spherical cage

作者：Li Yan; Li Yang Guang; Zhang Zhi Ming; Wu Qiong; Wang En Bo

来源：Inorganic Chemistry Communications, 2009, 12(9): 864-867.

DOI：10.1016/j.inoche.2009.06.033

• Cage magnetism
• Polyoxotungstate
• Vanadium

We report the {W72V30} composed of 12 pentagonal {(W)W-5} units and 30 [VO(H2O)](2 ) linkers. This compound was characterized by the elemental analysis, thermogravimetry, X-ray diffraction analysis, spectroscopic methods (IR, UV/Vis, Raman), XPS, EPR, magnetic measurements and BVS calculations. This is the second member in the pentagonal {(W)W5}-based polyoxotungstate family.

• 出版日期2009-9
• 单位东北师范大学