A series of compounds based on the Anderson-type polyoxoanions and Cu-amino acid complexes

作者：Zhang, Peng-Peng; Peng, Jun^*; Tian, Ai-Xiang; Sha, Jing-Quan; Pang, Hai-Jun; Chen, Yuan; Zhu, Min; Wang, Yong-Hui

来源：Journal of Molecular Structure, 2009, 931(1-3): 50-54.

DOI：10.1016/j.molstruc.2009.05.020

• Anderson-type polyoxoanions
• Sodium cations
• Amino acids
• Conventional synthesis

Three new compounds, [Cu(C6H8N3O2)C6H9N3O2)(H2O)(2)][Na(H2O)(2)](2)[Al(OH)(6)Mo6O18]center dot 6H(2)O (1). [Cu(C6H8-N3O2)(C6H9N3O2)(H2O)(2)][Na(H2O)](2)[Cr(OH)(6)Mo6O18]center dot 3H(2)O (2) and [Cu(C6H10N3O2)(C6H9N3O2)(H2O)(2)][Al(OH)(6)Mo6O18]center dot 9H(2)O (3) have been synthesized and characterized by elemental analyses, IR, TG, and single crystal X-ray diffraction. In the structures of compounds 1 and 2, the sodium cations connected the Anderson-type polyoxoanions to form 1D zigzag chains, which are connected to 2D layers by the Cu-histidine complexes. Compound 3 is a contrast for them, when the reactant without sodium cations is used, a discrete structure is formed.

• 出版日期2009-8-14
• 单位佳木斯大学; 东北师范大学