An Unusual Metallic Oxygen Cluster Consisting of a {AlMo12O40(MoO2)}

作者：Han Zhan Gang^*; Chang Xiao Qing; Yan Jin Shuang; Gong Kai Ning; Zhao Chuan; Zhai Xue Liang

来源：Inorganic Chemistry, 2014, 53(2): 670-672.

DOI：10.1021/ic402126e

A novel aluminum-containing, bimolybdenum-capped Keggin-type polyoxomolybate cluster of the {AlMo12O40(MoO2)(2)} anion has been synthesized and characterized. This is the first experimentally determined Keggin-type {AlMo12O40} polyoxoanion. The polyoxometalate crystal exhibits high selectivity toward the heterogeneous catalytic oxidation of cyclohexanol to cyclohexanone.

• 出版日期2014-1-20
• 单位河北师范大学