alpha-Substituted Boron Difluoride Acetylacetonates

作者:Svistunova I V*; Fedorenko E V
来源:Russian Journal of General Chemistry, 2008, 78(8): 1515-1523.
DOI:10.1134/S1070363208080094

摘要

By treatment of a-substituted acetylacetone derivatives with boron trifluoride etherate a series of earlier unknown boron difluoride complexes is obtained. The series includes binuclear complexes containing boron in the chelate fragment connected via sulfur or selenium atom. Gas chromatographic and spectral characteristics of the obtained compounds were investigated. By means of chromato-mass spectrometry their reaction with hydrazine in acidic and alkaline media was studied.

  • 出版日期2008-8