Dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of a quadruple bonded Mo-2 core

作者：Tsurugi Hayato; Yamada Kohei; Majumdar Moumita; Sugino Yoshitaka; Hayakawa Akio; Mashima Kazushi^*

来源：Dalton Transactions, 2011, 40(37): 9358-9361.

DOI：10.1039/c1dt11129a

We developed dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of the Mo-2 core. A 2,4,6-triisopropylbenzoate-supported Mo-2 complex acts as a catalyst for radical addition reactions of polyhaloalkanes to 1-alkenes and cyclopentene, while amidinate-and guanidinate-supported Mo-2 clusters are effective catalysts for the radical polymerization reaction of methyl methacrylate.

• 出版日期2011