Diamond synthesis in aluminum matrix in molten alkali-halide at ambient pressure

作者：Yolshina L A^*; Muradymov R V; Vovkotrub E G; Smirnov S V

来源：Diamond and Related Materials, 2015, 55: 1-11.

DOI：10.1016/j.diamond.2015.02.005

• Cubic diamond
• Nanodiamond
• Synthesis
• Molten salts
• Aluminum matrix
• Diffusion

The interaction of the molten aluminum with the carbon-containing admixture in a molten halide-alkali medium at atmospheric pressure with temperatures of 700-800 degrees C under strong non-equilibrium conditions is studied. Cubic diamond crystals of 2-100 mu m and nanorods of 20-100 nm diameter and 5 mu m lengths are first found forming inside the aluminum matrix under certain cooling regimes. The X-ray diffraction analysis, electron backscatter diffraction spectroscopy, electronic microscopy, Raman spectroscopy and microhardness detection register the perfect cubic diamond formation inside aluminum without applying of high temperature and high-pressure. Diamond formation mechanism is growing by carbon atom diffusion through an aluminum droplet. Diamond and nanodiamond synthesis conducted directly at the carbon ion interaction with the molten metal volume and subsequent cooling regimes.
Prime novelty statement: Diamond synthesis has been performed in molten aluminium via the interaction between molten aluminium and carbide-containing halide melt at 700-750 degrees C with ambient pressure.
The X-ray diffraction analysis, electron backscatter diffraction spectroscopy, electronic microscopy, Raman spectroscopy and microhardness detection register the perfect cubic diamond formation inside aluminium without high temperatures and high-pressure regimes.

• 出版日期2015-5