A new strategy for the construction of a single-walled metal-organic nanotubular framework: utilizing "T"-shaped building unit with ligand modification

作者：Liu Bao Yu; Liu Feng; Lv Li Hong; Grajeda Javier; Huang Xiao Chun^*

来源：CrystEngComm, 2013, 15(3): 447-450.

DOI：10.1039/c2ce26350e

Two coordination compounds, Cu(pim) (1) and Cu-2(ppt)center dot 1.5H(2)O (2) (Hpim = 2-(4-pyridyl)-imidazole, H(2)ppt = 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol), based on ligands with a "T"-shaped structural unit were reported here. 1 presents a 2D layer network, whereas 2 shows a MOF containing a 1D tubular channel, which are constructed utilizing a similar unit to the 2D layer in 1, representing a new strategy to construct tubular frameworks. Furthermore, basic properties such as photoluminescence and gas adsorption have been investigated as well.

• 出版日期2013
• 单位汕头大学