Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

作者：Chen Tzu Tso; Chen Yu Sen; Chang Ya Ho; Wang Jung Ching; Tsai Yi Fang; Lee Gene Hsiang; Kuo Tin Shen; Hsu Hua Fen^*

来源：Chemical communications, 2013, 49(11): 1109-1111.

DOI：10.1039/c2cc37801a

A V-III thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V-III-Cl species (major one) and a V-IV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

• 出版日期2013