Microporous Cobalt(II)-Organic Framework with Open O-Donor Sites for Effective C2H2 Storage and C2H2/CO2 Separation at Room Temperature

作者：Chen, Di-Ming; Liu, Xiao-Hui; Tian, Jia-Yue; Zhang, Jia-Hui; Liu, Chun-Sen^*; Du, Miao^*

来源：Inorganic Chemistry, 2017, 56(24): 14767-14770.

DOI：10.1021/acs.inorgchem.7b02764

• METAL-ORGANIC FRAMEWORK
• GAS-ADSORPTION
• CARBON-DIOXIDE
• ACETYLENE
• INTERPENETRATION
• CAPACITY
• CO2

The self-assembly of a bifunctional organic ligand with a formate-bridged rod-shaped secondary building unit leads to a new microporous metal-organic framework (MOF). This MOF shows a moderately high C2H2 storage capacity (145 cm(3)/g) and an excellent adsorption selectivity for C2H2/CO2 (11) at room temperature. Furthermore, its discriminatory sorption behavior toward C2H2 and CO2 was probed by computational analysis in detail.

• 出版日期2017-12-18
• 单位郑州轻工业大学