A (3,8)-connected metal-organic framework with a unique binuclear [Ni-2(mu(2)-OH)(COO)(2)] node for high H-2 and CO2 adsorption capacities

作者：Zhang, Lei; Qian, Jinjie; Yang, Wenbin; Kuang, Xiaofei; Zhang, Jun; Cui, Yixin; Wu, Weiming; Wu, Xiao-Yuan; Lu, Can-Zhong^*; Chen, Wen-Zhe

来源：Journal of Materials Chemistry A, 2015, 3(30): 15399-15402.

DOI：10.1039/c5ta03493k

• CARBON-DIOXIDE CAPTURE
• HYDROGEN-STORAGE
• LIGAND
• PARTITION
• DESIGN
• UNITS

A rare binuclear [Ni-2(mu(2)-OH)(COO)(2)]-based nickel-organic framework (1) composed of close-packed irregular octahedral cages possesses a new ( 3,8)-connected topology with the Schlafli symbol of (3.5(2))(2)(3(4).4(2).5(6).6(11).7(4).8). At 10 bar, this activated sample (1a) exhibits a considerably high H-2 uptake of 203.2 cm(3) g(-1) (1.81 wt%) at 77 K, and a high CO2 uptake of 108.2 cm(3) g(-1) (21.3 wt%) at 273 K. In addition, 1a has good adsorption selectivity for CO2 over CH4 and N-2.

• 出版日期2015
• 单位中国科学院福建物质结构研究所; 福州大学; 厦门理工学院