An unprecedented one-step synthesis of octahedral Cu(II)-bis(iminoquinone) complexes and their reactivity with NaBH4

作者：Mondal Manas Kumar; Mukherjee Chandan

来源：Dalton Transactions, 2016, 45(34): 13532-13540.

DOI：10.1039/c6dt02443b

The non-innocent ligands, H2LAP(o-NO2-OPh) and H2LAP, upon reacting with 2 equivalents of CuCl2·2H2O in the presence of Et3N and air provided the corresponding octahedral Cu(ii)-bis(iminoquinone) complexes (<bold>2</bold> and <bold>3</bold>) in one-step. The complexes underwent reduction by NaBH4 in dry CH3CN and produced H2 gas.

• 出版日期2016-9-14