A novel 3D metal-organic coordination polymer constructed from two types of tetranuclear copper clusters and a flexible bispyridyl-based ligand with amide-(CH2)(6) bridge

作者：Wang Xiuli^*; Liu Peng; Lin Hongyan; Xu Chuang; Zhang Juwen; Liu Guocheng

来源：Inorganic Chemistry Communications, 2013, 30: 79-83.

DOI：10.1016/j.inoche.2013.01.015

• Metal-organic coordination polymer
• Tetranuclear copper cluster
• Flexible bis-pyridyl-bis-amide ligand
• Magnetic property

A new 3D metal-organic coordination polymer with an unusual 3,3,8,8-connected {4.5.6}(4){4(2).5(8).6(12).7(3).8(3)}{4(2).5(9).6(14).7.8(2)} topology has been synthesized under hydrothermal condition, [Cu-4(BTC)(2)(L)(mu(3)-OH)(2)(H2O)]center dot 6H(2)O (1) [L=N,N'-bis(3-pyridinecarboxamide)-1,6-hexane, H3BTC=1,3,5-benzenetricarboxylic acid], which represents the first example of metal-organic frameworks based on two types of tetranuclear copper clusters [Cu-4(mu(3)-OH)(2)(O2C-)(6)] and flexible bis-pyridyl-bis-amided based ligand. Moreover, the electrochemical behavior and magnetic property of I have been investigated.

• 出版日期2013-4
• 单位渤海大学