摘要
N-Benzyl pentahydroxyazepanes undergo ring isomerization during mesylation of the hydroxyl group beta to the nitrogen via a neighboring nitrogen participation involving a transient aziridinium species which is trapped by chlorine. The resulting chloromethyl tetrahydroxypiperidines have been converted into the corresponding homoglyconojirimycins.
- 出版日期2007-4-3
- 单位浙江大学