A New 2D Coordination Polymer Material Based on 4d-4f Heterometallic Assembly

作者：Wu, Jian; Liu, Jian-Qiang^*

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2010, 40(1): 27-31.

DOI：10.1080/15533170903492713

• crystal structure
• heterometallic complex
• porous framework

A new transition-lanthanide metal-organic framework coordination complex, namely [Ag2Dy(nic)4(H2O)4 center dot ClO4 center dot H2O]n (nic = nicotinate) (1) has been synthesized by the reaction of the 4d and 4f metal salts with heterocyclic ligand under mild condition and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compound 1 presents interesting 2D under heterometallic layer generated by the self-assembly of 1D chains of lanthanide-carboxylate with Ag(nic)2 subunits. Furthermore, the title compound displays an interesting 3D zeolite-like porous topology.

• 出版日期2010
• 单位广东医科大学; 广西民族大学