A Facile Approach to Prepare Multiple Heteroatom-Doped Carbon Materials from Imine-Linked Porous Organic Polymers

作者：Yang, Juan; Xu, Min; Wang, Jingyu^*; Jin, Shangbin^*; Tan, Bien

来源：Scientific Reports, 2018, 8(1): 4200.

DOI：10.1038/s41598-018-22507-2

• OXYGEN REDUCTION REACTION
• HIGHLY EFFICIENT ELECTROCATALYSTS
• MICROPOROUS POLYMERS
• PHOSPHORIC-ACID
• CO2 CAPTURE
• NITROGEN
• GRAPHENE
• EVOLUTION
• FRAMEWORK
• CATALYSTS

In this paper, we proposed a new strategy to prepare multiple heteroatom doped (N, P-doped) porous carbon materials with high surface area of similar to 1,535 m(2) g(-1) simply by pyrolysis of imine-linked porous organic polymers (POPs) synthesized via Schiff base condensation. The strategy is simple without any post-processing and various heteroatoms could be involved. Scanning electron microscopy, Raman spectra, Nitrogen gas adsorption-desorption, X-ray photoelectron spectroscopy have been used to characterize the morphology, the structure and the composition of the materials. The multiple heteroatom doped porous carbon materials also display high electrocatalytic performance as exampled by the application in oxygen reduction, which showed the catalyst favors 4-electron transfer during the process, along with superior stability and higher tolerance to methanol as compared to the Pt/C. These results indicate the present method is promising for the preparation of multi-heteroatom doped carbon materials in the application of electrocatalysis.

• 出版日期2018-3-9
• 单位华中科技大学