Nonlinear optical activity and high thermal stability of a new 3D open-framework with interconnected 24-, 16-, and 8-atom channels: (NH4)Zn[O3PCH(OH)CO2]

作者：Fu RB; Zhang HS; Wang LS; Hu SM; Li YM; Huang XH; Wu XT^*

来源：European Journal of Inorganic Chemistry, 2005, 2005(16): 3211-3213.

DOI：10.1002/ejic.200500347

• zinc
• hydroxy(phosphonoato)acetate
• nonlinear optical activity
• hydrothermal synthesis
• open-framework

Hydrothermal. reaction of hydroxy(phosphono)acetic acid, H2O3PCH(OH)CO2H, with zinc(II) acetate resulted in a new ammonium zinc hydroxy(phosphonato) acetate, (NH4)-Zn[O3PCH(OH)CO2] (1). The structure of 1 contains a 3D open-framework consisting of interconnected 24-, 16-, and 8-atom channels. TGA and XRD reveal that the framework is stable up to 350 degrees C in air. Its powder SHG intensity is about 0.

• 出版日期2005-8-19
• 单位中国科学院福建物质结构研究所