Acetonitriledicarbonyl(eta(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate

作者：M'thiruaine Cyprian M; Friedrich Holger B; Changamu Evans O; Bala Muhammad D^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M924-U969.

DOI：10.1107/S1600536811021350

In the structure of the title compound, [Fe{eta(5)-C-5(CH3)(5)}(NCCH3)(CO)(2)]BF4, the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe-N bond length is 1.924 (3) angstrom and the Fe-Cp* centroid distance is 1.722 angstrom.

• 出版日期2011-7