Adsorption of two gas molecules at a single metal site in a metal-organic framework

作者:Runcevski Tomce; Kapelewski Matthew T; Torres Gavosto Rodolfo M; Tarver Jacob D; Brown Craig M; Long Jeffrey R
来源:Chemical Communications, 2016, 52(53): 8251-8254.
DOI:10.1039/c6cc02494g

摘要

One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules-specifically hydrogen, methane, or carbon dioxide.

  • 出版日期2016