Layered Perovskite Oxide: A Reversible Air Electrode for Oxygen Evolution/Reduction in Rechargeable Metal-Air Batteries

作者：Takeguchi Tatsuya^*; Yamanaka Toshiro; Takahashi Hiroki; Watanabe Hiroshi; Kuroki Tomohiro; Nakanishi Haruyuki; Orikasa Yuki; Uchimoto Yoshiharu; Takano Hiroshi; Ohguri Nobuaki; Matsuda Motofumi; Murota Tadatoshi; Uosaki Kohei; Ueda Wataru

来源：Journal of the American Chemical Society, 2013, 135(30): 11125-11130.

DOI：10.1021/ja403476v

For the development of a rechargeable metal-air battery, which is expected to become one of the most widely used batteries in the future, slow kinetics of discharging and charging reactions at the air electrode, i.e., oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), respectively, are the most critical problems. Here we report that Ruddlesden-Popper-type layered perovskite, RP-LaSr3Fe3O10 (n = 3), functions as a reversible air electrode catalyst for both ORR and OER at an equilibrium potential of 1.23 V with almost no overpotentials. The function of RP-LaSr3Fe3O10 as an ORR catalyst was confirmed by using an alkaline fuel cell composed of Pd/LaSr3Fe3O10-2x(OH)(2x)center dot H2O/RP-LaSr3Fe3O10 as an open circuit voltage (OCV) of 1.23 V was obtained. RP-LaSr3Fe3O10 also catalyzed OER at an equilibrium potential of 1.23 V with almost no overpotentials. Reversible ORR and OER are achieved because of the easily removable oxygen present in RP-LaSr3Fe3O10. Thus, RP-LaSr3Fe3O10 minimizes efficiency losses caused by reactions during charging and discharging at the air electrode and can be considered to be the ORR/OER electrocatalyst for rechargeable metal-air batteries.

• 出版日期2013-7-31