Novel chromophores with excellent electro-optic activity based on double-donor chromophores by optimizing thiophene bridges

作者：Yang, Yuhui; Bo, Shuhui; Wang, Haoran; Liu, Fenggang; Liu, Jialei; Qiu, Ling; Zhen, Zhen; Liu, Xinhou^*

来源：Dyes and Pigments, 2015, 122: 139-146.

DOI：10.1016/j.dyepig.2015.06.012

• Double-donor chromophores
• Electro-optic
• Isolation group
• Poled film
• NLO
• DFT

Three novel nonlinear optical chromophores based on the same bis(N,N-diethyl)aniline donor have been synthesized and systematically characterized. These chromophores showed good thermal stability and chromophore y1 showed the best thermal stability of 249 degrees C. Besides, compared with the chromophore (y1) without the substituted group, chromophores y2 and y3 show better intramolecular charge-transfer absorption. Most importantly, the high molecular hyperpolarizability of these chromophores can be effectively translated into large electro-optic coefficients. The electro-optic coefficient of poled films containing 25% wt of chromophores y1-y3 doped in amorphous polycarbonate afforded values of 149, 138 and 157 pm/V at 1310 nm for chromophores y1-y3 respectively. These results indicated that the double donors of bis(N,N-diethyl)aniline unit can efficiently improve the electron-donating ability and the special structure can reduce intermolecular electrostatic interactions, thus enhancing the macroscopic electro-optic activity. These properties, together with good solubility, suggest the potential use of these chromophores as advanced materials.

• 出版日期2015-11
• 单位中国科学院理化技术研究所; 中国科学院大学