A novel POM-based inorganic porous framework: Synthesis, structure and properties

作者：Sun Yingying; Lu Jing^*; Li Dacheng; Dou Jianmin

来源：Inorganic Chemistry Communications, 2013, 36: 166-169.

DOI：10.1016/j.inoche.2013.08.027

• Multifunctional porous material
• Adamantane network
• Helical chain

A novel POM-based inorganic porous framework, (H(2)en)(3)[Mn3P4Mo4O28] 1 (en = ethylenediamine),has been hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TG analyses, and single crystal X-ray diffraction. In compound 1, PO4 groups link Mn atoms to form three-fold interpenetrated adamantane networks; the Mo-O helical chains connect with the adamantane networks through mu(2)-bridging oxygen atoms and PO4 groups. The PO4, MnO4, MnO6 and MoO6 polyhedrons share corners and connect with each other to form a 3-D complicated framework with 1-D channels. And the channels are filled with the diprotonated ethylenediamine cations. The magnetic behavior of 1 is antiferromagnetic coupling. Futhermore, compound 1 exhibits good thermal stability and active electrochemical behavior.

• 出版日期2013-10
• 单位聊城大学