A Heterometallic, Heterovalent Cu-I/Sn-II/IV/S Cluster with an Unprecedented Cu4Sn Core and Stannacyclopentane Units

作者：Nayek Hari Pacla; Massa Werner; Dehnen Stefanie^*

来源：Inorganic Chemistry, 2008, 47(20): 9146-9148.

DOI：10.1021/ic8013877

[(Ph3PCuI)(6){(CH2)(4)(SnS2)-S-IV}6Cu(4)(I)Sn(II)], a walnut-type, heterometallic, heterovalent cluster, as confirmed by density functional theory calculations, was obtained under reductive solvothermal conditions and features an unprecedented metalloid core within a metal sulfide shell and an organic surface.

• 出版日期2008-10-20