科研之友
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摘要
Direct carboxylation of acetylene with CO2 was carried out in the presence of 1,5,7-triazabicyclo[4.4.0]dec-1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO2 and by producing valuable chemical feed stocks.
- 出版日期2013-4
