A new heterometallic coordination polymer: Synthesis, structure, and catalytic property

作者：Liu, Qi-Feng; Liu, Wei; Cao, Yi-Po; Dong, Yan-Li; Liu, Hui-Min^*

来源：Inorganic and Nano-Metal Chemistry, 2017, 47(1): 153-157.

DOI：10.1080/15533174.2016.1158188

• Catalytic property
• heterometallic compound
• solvothermal reaction
• topology

A new heterometallic-organic framework, namely [CuCa(tdc)(2)(DMF)](n) (1 H(2)tdc = 2,5-thiophenedicarboxylic acid, DMF = N, N'-dimethylformamide), has been successfully obtained through the solvothermal reactions of CuCl2, Ca(NO3)(2), and H(2)tdc. Single-crystal structural analysis reveals that compound 1 features a 3D framework with the irl topology. Compound 1 has potential unsaturated metal sites after the removal of the coordinated DMF molecules, so it exhibits excellent catalytic activity for the diethylzinc addition to benzaldehyde.

• 出版日期2017
• 单位河北农业大学