摘要

As a highly economic and efficient strategy for chemical bond formation, oxidative coupling has been widely applied in synthetic organic chemistry. Recently, Klussmann, Jiao and Huo et al. groups have successfully achieved the direct functionalization of Csp(3)-H and Csp(2)-H bonds through developing simple, elegant autoxidative coupling reactions, which makes a significant progress in this filed. This highlight mainly reviews the recent advances in autoxidative coupling.