A eutectic effect in the formation of coal based mesophase pitch

作者：Cheng Xiang lin^*; Zha Qing fang; Li Xue jun; Yang Xiao jun

来源：New Carbon Materials, 2009, 24(1): 50-54.

DOI：10.1016/j.carbon.2009.03.017

• Coal tar pitch
• Waste polystyrene
• Alkylation
• Co-carbonization
• Eutectic effect

The toluene soluble part of coal tar pitch (TS) was co-carbonized with waste polystyrene (WPS) to produce mesophase pitch. Results showed that the properties of the mesophase were improved greatley due to the eutectic effect. The solubilities of the TS mesophase pitch and TS-WPS mesophase pitch were mass fraction of 10 and 52% respectively. The anisotropic volume fractions of the TS mesophase pitch and TS-WPS mesophase pitch were 65% (coarse mosaie texture) and 100% (flow domain texture) respectively. Apparent viscosities showed that the mesophase pitch was changed from thixotropic to unthioxotropic by adding WPS to TS. FT-IR and (1)H-NMR spectroscopy showed that an alkylation reaction took place accompanied by an increase of methylene groups when WPS was added to TS. The increase of alkyl groups led to an assembly of mesogen molecules, resulting in a eutectic effect.

• 出版日期2009-3
• 单位中国石油大学（北京）