Assembly of discrete linear (H2O)(5) water cluster within an entangled two-dimensional coordination network

作者：Liu Dong^*; Li Ni Ya; Deng Fan Zheng; Wang Yu Feng; Xu Yun; Xie Guang Yu; Zheng Zi Liang

来源：Journal of Molecular Structure, 2013, 1034: 271-275.

DOI：10.1016/j.molstruc.2012.10.030

• Water clusters
• Assembly
• Coordination polymer
• Hydrogen-bonding interactions

The coordination polymer {[Zn-2(1,3-pda)(2)(bpp)(2)]center dot 5H(2)O}(n) (1) (1,3-H(2)pda = 1,3-phenylene-diacrylic acid, bpp = 1,3-bis(4-pyridyl)-propane) was obtained from the hydrothermal reaction of Zn(NO3)(2)center dot 6H(2)O, 1,3-H(2)pda, bpp in a 1:1:1 molar ratio in the presence of NaOH. Single-crystal X-ray diffraction analysis reveals that I is a two-fold interpenetrating two-dimensional network containing small cavities. Within each cavity of the entangled network, five water molecules are aggregated to form an unique discrete linear (H2O)(5) water cluster. Thermal and luminescent properties of 1 were also investigated.

• 出版日期2013-2-27
• 单位淮北师范大学