Postsynthesis Modification of a Porous Coordination Polymer by LiCl To Enhance H+ Transport

作者：Horike Satoshi^*; Kamitsubo Yusuke; Inukai Munehiro; Fukushima Tomohiro; Umeyama Daiki; Itakura Tomoya; Kitagawa Susumu

来源：Journal of the American Chemical Society, 2013, 135(12): 4612-4615.

DOI：10.1021/ja3122872

A Ca2+ porous coordination polymer with ID channels was functionalized by the postsynthesis addition of LiCl to enhance the H+ conductivity. The compound showed over 10(-2) S cm(-1) at 25 degrees C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H+ conductivity was achieved by the support of Li+ ion movements in the channel.

• 出版日期2013-3-27