A highly sensitive fluorescence method reveals the presence of palladium in a cross-coupling reaction mixture not treated with transition metals

作者：Inamoto Kiyofumi^*; Campbell Laura D; Doi Takayuki; Koide Kazunori

来源：Tetrahedron Letters, 2012, 53(25): 3147-3148.

DOI：10.1016/j.tetlet.2012.04.043

• Palladium
• Suzuki-Miyaura coupling
• Sensor
• Fluorescence spectroscopy
• Catalysis

We previously reported a Suzuki-Miyaura coupling in dimethyl carbonate without adding additional transition metals. Here, we show an analysis of the reaction mixture that revealed the presence of palladium using a fluorogenic Tsuji-Trost reaction.

• 出版日期2012-6-20