摘要

Piezoelectric energy harvesting is a hotspot in the field of new energy, the core goal of which is to prepare piezoceramics with a high transduction coefficient (d(33)xg(33)). The traditional solid-solution design strategy usually causes the same variation trend of d(33) and epsilon(r), resulting in a low d(33)xg(33) value. In this work, a composite design strategy was proposed that uses PZN-PZT/ZnAl2O4 as an example. By introducing WZnAl2O4, which is nonferroelectric with low epsilon(r), to the PZN-PZT piezoelectric matrix, epsilon(r) decreased rapidly while d(33) remained relatively stable. This behavior was ascribed to the increase of Q(33) caused by an interfacial effect facilitating the formation of micro-domain structure.