A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties

作者：Lu, J. F.^*; Tang, Z. H.; Shi, J.; Ge, H. G.; Jiang, M.; Song, J.; Jin, L. X.^*

来源：Crystallography Reports, 2017, 62(7): 1041-1045.

DOI：10.1134/S1063774517070161

• METAL-ORGANIC FRAMEWORKS
• LUMINESCENT PROPERTY
• POROUS MATERIAL
• LIGANDS
• 1D
• 2D

The title compound {[Co-3(mu(3)-OH)(mu(2)-H2O)(2)(H2O)(5)(BTC)(2)]center dot 6H(2)O}(n) (H3BTC is a 1,3,5-benzenetricarboxylic acid) was prepared and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and elemental analyses. The single crystal X-ray diffraction reveals that the title compound consists of 1D infinite zigzag chains which were constructed by trinuclear cobalt cluster and BTC3- ligand. Neighbouring above-mentioned 1D infinite zigzag chains are further linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. In addition, the luminescent properties of the title compound were investigated.

• 出版日期2017-12
• 单位陕西理工大学