Aqua{6,6 '-dimethoxy-2,2 '-[ethane-1,2diylbis(nitrilomethylidyne)]diphenolato-kappa O-4,N,N ',O '}cobalt(II)

作者：Jiang, Gang Biao; Zhang, Shu Hua; Zeng, Ming Hua^*

来源：ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63: M2383-U1246.

DOI：10.1107/S1600536807039487

In the title compound, [Co(C18H18N2O4)(H2O)], the Co-II atom is coordinated in a distorted square-pyramidal geometry defined by two O atoms and two N atoms in the basal positions, and one water molecule in the apical position. The Co-II atom and water O atom lie on a symmetry plane defining C-s molecular symmetry. In the crystal structure, the ethylenediamine group is disordered over two positions with equal occupancy. Molecules are linked into chains via O - H center dot center dot center dot O hydrogen bonds.

• 出版日期2007-9
• 单位广西师范大学; 华南农业大学