mu-Benzene-1,2,4,5-tetracarboxylato-bis[aquabis(2,2 '-bipyridine)cobalt(II)] dodecahydrate

作者:Tabatabaee Masoumeh*; Ghassemzadeh Mitra; Rezaie Fatemeh; Khavasi Hamid Reza; Amini Mostafa M
来源:Acta Crystallographica Section E-Structure Reports Online, 2006, 62: M2784-M2785.
DOI:10.1107/S1600536806039559

摘要

A new cobalt complex, [Co(2)(C(10)H(2)O(8))(C(10)H(8)N(2))(4)(H(2)O)(2)]center dot 12H(2)O, has been hydrothermally synthesized at 413 K over a period of 8 h. Its structure has been determined by single-crystal X-ray diffraction analysis. Each metal ion center is in a distorted octahedral geometry and coordinated by four N atoms from the two 2,2'-bipyridine ligands, an O atom from H(2)O and an O atom from the bridging benzene-1,2,4,5-tetracarboxylate ligand. There is a center of inversion at the center of the benzene ring.

  • 出版日期2006-11