Ultrafine NaTi2(PO4)3 Nanoparticles Encapsulated in N-CNFs as Ultra-Stable Electrode for Sodium Storage

作者：Yu, Sicen; Wan, Yi; Shang, Chaoqun; Wang, Zhenyu; Zhou, Liangjun; Zou, Jianli; Cheng, Hua^*; Lu, Zhouguang^*

来源：Frontiers in Chemistry, 2018, 6: 270.

DOI：10.3389/fchem.2018.00270

• NTP
• N-doping carbon nanofibers
• cycling performance
• electrospinning
• sodium-storage

We present a feasible method for the preparation of one-dimensional N-doping carbon nanofibers encapsulated NaTi2(PO4)(3) (NTP-NCNFs) through electrospinning accompanied by calcination. The poor electrical conductivity of NTP is significantly improved and the as-prepared NTP-NCNFs exhibit stable and ultrafast sodium-storage capability. The NTP-NCNFs maintains a stable specific capacity of 121 mAh g(-1) at 10C after 2,000 cycles, which only drop to 105 mAh g(-1) after 20,000 cycles. Furthermore, the NTP-NCNFs show excellent rate performance from 0.2 to 20 C, whose recovery efficiency still reaches 99.43%. The superior electrochemical property is mainly attributed to the large specific surface area, high porosity, N-doping carbon coating, and one-dimensional structure of NTP-NCNFs.

• 出版日期2018-7-6