NHC-AuCl/Selectfluor: A Highly Efficient Catalytic System for Carbene-Transfer Reactions

作者：Ma, Jun; Jiang, Huanfeng; Zhu, Shifa^*

来源：Organic Letters, 2014, 16(17): 4472-4475.

DOI：10.1021/ol502018d

• GOLD CATALYSIS
• BIS(ALKYNE) COMPLEXES
• LIGAND DESIGN
• CYCLOPROPANATION
• GENERATION
• ALCOHOLS
• TRIS(ALKYNE)
• ALKENES
• ALKYNES
• FURANS

The combination of NHC-gold complex and Selectfluor has been found to be a highly efficient catalyst system for carbene-transfer reactions, with a turnover number (TON) up to 990000 and a turnover frequency (TOF) up to 82500 h(-1).

• 出版日期2014-9-5
• 单位华南理工大学