A concise stereoselective total synthesis of diplodialide C

作者：Pratapareddy Bommareddy; Sreenivasulu Reddymasu; Hatti Islavathu; Rao Mandava Venkata Basaveswara^*; Raju Rudraraju Ramesh

来源：Monatshefte fur Chemie, 2015, 146(11): 1921-1926.

DOI：10.1007/s00706-015-1464-1

• Homoallylic alcohol
• Cross-metathesis reaction
• Yamaguchi macrolactonization
• Diplodialide C

An asymmetric total synthesis of diplodialide C has been achieved starting from commercially available homoallylic alcohol. Regioselective opening of the chiral epoxide, cross-metathesis reaction, and Yamaguchi macrolactonization were used as the key steps in this synthesis.
[GRAPHICS]
.

• 出版日期2015-11