A semiconducting microporous framework of Cd6Ag4(SPh)(16) clusters interlinked using rigid and conjugated bipyridines

作者:Xu Chao; Hedin Niklas*; Shi Hua Tian; Zhang Qian Feng
来源:Chemical communications, 2014, 50(28): 3710-3712.
DOI:10.1039/c3cc49660k

摘要

Ternary supertetrahedral chalcogenolate clusters were interlinked with bipyridines into a microporous semiconducting framework with properties qualitatively different from those of the original clusters. Both the framework and the clusters were effective photocatalysts, and rapidly degraded the dye rhodamine B.