Morphology evolution of NaTaO3 submicrometer single-crystals: from cubes to quasi-spheres

作者：Chen, Wei; Kuang, Qin^*; Xie, Zhaoxiong

来源：Science China-Materials, 2015, 58(4): 281-288.

DOI：10.1007/s40843-015-0041-6

• TANTALATE PHOTOCATALYSTS
• SOLVOTHERMAL SYNTHESIS
• BOTTOM-UP
• WATER
• H-2
• O-2
• DECOMPOSITION
• EXTINCTION
• PERCENTAGE
• FACETS

Surface structure control of functional nano-/micro-crystallites has attracted great attention because many important physicochemical properties depend on their surface. Guided by the supersaturation-dependent surface structure evolution strategy we proposed recently, NaTaO3 submicrometer crystals with morphologies of cubes, corner truncated cubes, edge and corner truncated cubes, and quasi-spheres can be synthesized by changing the volume ratio of ethylene glycol to water and the amount of NaOH in the composite solvent. Under low supersaturation condition, NaTaO3 cubic crystals with low energy {100} facets were obtained. As the supersaturation increases, the corners and edges of NaTaO3 cubic crystals, which possess higher surface energy, were gradually truncated. Surprisingly, quasi-sphere crystallites formed under extremely high supersaturation condition, which is difficult to be explained by the classical crystal growth theories. By analyzing the formation work of two-dimension crystal nuclei, we concluded that the crystal growth tend to be isotropic at extremely high supersaturation, which well explained the formation of the quasi-sphere crystallites.

• 出版日期2015-4
• 单位厦门大学