A novel low temperature vapor phase hydrolysis method for the production of nano-structured silica materials using silicon tetrachloride

作者：Chen Xuejing; Jiang Jianguo^*; Yan Feng; Tian Sicong; Li Kaimin

来源：RSC Advances, 2014, 4(17): 8703-8710.

DOI：10.1039/c3ra47018k

• Chemical compositions
• Chemical functional groups
• Environmentally benign
• Hydrolysis methods
• Optimal synthesis
• Particle morphologies
• Reaction temperature
• Silicon tetrachloride

Here we report for the first time, a novel method of low temperature vapor phase hydrolysis for the production of nano-structured silica particles. Silica nanoparticles were obtained by the hydrolysis of silicon tetrachloride vapor with water vapor at a low temperature range (150-250 degrees C). The effects of reaction temperature and residence time on the specific surface area and size distribution were determined to obtain optimal synthesis conditions. Silica nanoparticles with a specific surface area of 418 m(2) g(-1) and an average size of 141.7 nm were obtained at a temperature of 150 degrees C and with a residence time of 5 s. The particle morphology, phase composition, chemical composition, thermal analysis, and chemical functional groups present were determined by TEM, XRD, XRF, TGA, and IR methods, respectively. Results indicated that silica synthesized by low temperature vapor phase hydrolysis method is an amorphous mesoporous material, with an approximately spherical shape, a mass friction demission of 2.29, and a high hydroxyl density of 13.03 nm(-2). This method provides a simple and environmentally benign way for the mass production of silica nanoparticles, as well as a quick method for the preparation of functional silica materials.

• 出版日期2014
• 单位清华大学